When it comes to “friends” in Wendy’s head, Vanessa Williams has always been at the top of the list.

Her muy caliente “Ugly Betty” co-star Adam Rodriguez stopped by the show today and Wendy wasted no time trying to play matchmaker.

Take a look!

The wait is finally over. You can buy Whitney Houston’s new album, I Look to you, at iTunes now!

Watch Wendy’s shout out to Whitney here and these other “Whitney Moments” from the show.

After Hot Topics, Wendy welcomed the incomparable, Vanessa Williams, as her first guest!

Vanessa congratulated Wendy on the honor of receiving a proclamation from the city of New York, declaring today, “Wendy Williams Day.” Watch the exclusive video as Wendy was surprised with this honor.

Vanessa Williams is "The Real Thing"

Then, Vanessa performed the title track off of her latest CD, “The Real Thing.” Make sure you buy your copy today.

For more info on Vanessa, visit her website, vanessawilliams.com.

Later in the show Wendy gave members of the audience advice in a segment we call “Ask Wendy.” If you have a question you want Wendy’s advice on, click here.

What Wendy’s Wearing?:
For the premiere show Wendy wore a pink long sleeve wrap blouse and ruched skirt from Norma Kamali with Christian Louboutins.

Accessories:
Hinge Mother of Pearl Bracelets: Pono by Joan Goodman
Earrings from Forever 21

What a week!

Vanessa Williams. Carson Kressley. NeNe. CeCe Peniston. The “Cake Boss” and a birthday celebration.

It’s been a great first week of “The Wendy Williams Show” and the party’s only getting started.

Take a look back at all the fun we had!